Both teams have won all four of their games up to this point but the Red Roses, backed by a home crowd and top of the standings, go into the final weekend as favourites to win a seventh consecutive title.
Elsewhere, Wales, Italy, and Scotland could all still finish with the wooden spoon.
The Welsh head to Parma hoping to avoid a winless tournament while Scotland host Ireland in Edinburgh.
RadioTimes.com brings you all the TV coverage details for the Women's Six Nations 2025.
Women's Six Nations 2025 on TV
Every game will be shown live on the BBC throughout the duration of the tournament.
At least one of the main linear BBC channels, including region-specific channels, will show each of the games, exposing millions to elite rugby union action on free-to-air TV.
Games will also be available to watch on BBC iPlayer and the BBC Sport website, so you don't have to miss a moment - even on the move.
You can tune in to each platform via a range of devices, including smart TVs, laptops and smartphones, meaning you can catch every tackle, turnover and try.
Women's Six Nations 2025 TV schedule
All UK time. All matches live on BBC iPlayer and BBC Sport website, plus channels specified below.
Round 5
Saturday 26th April
- Italy v Wales (12:15pm) BBC One Wales / BBC iPlayer / BBC Sport website
- Scotland v Ireland (2:30pm) BBC One Scotland / BBC iPlayer / BBC Sport website
- England v France (4:45pm) BBC Two / BBC iPlayer /BBC Sport website
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